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33. D. Voss, P. Krüger, and J. Pollmann, 1998, private communication. 34. R. Claessen, R. Anderson, J. Alien, C. Olson, C. Janowitz, W. Ellis, S. Harm, M. Kalning, R. Manzke, and M. Skibowski, Phys. Rev. Lett. 69, 808 (1992). 35. S. Harm, R. Dürig, R. Manzke, M. Skibowski, R. Claessen, and J. Alien, J. Electron 36. R. O. Anderson, G. W. P. Ellis, C. Janowitz, Spectr. Rel. Phen. 68, 111 (1994). G. X. Shen, V. Eyert, M. Skibowski, K. Friemelt, E. Bucher, and S. Hüfner, Phys. Rev. B 54, 2453 (1996).

Vac. Sci. Technol. B 3, 724 (1985). 27. 29. Y. Liang, Electronic Properties of Transition Metal Dichalcogenides and their Intercalation Complexes, Vol. 148 of Intercalation in Layered Materials (NATO ASI, Plenum Press, New York, 1986). 30. A. D. Yoffe, The transition metal dichalcogenides. Discussion and interpretation of the observed optical, electrical and structural properties, Vol. 18 of Advances in Physics (Taylor & Francis LTD, London, 1969). 31. R. Manzke and M. Skibowski, in Electronic Structure of Solids: Photoemission Spec- tra and Related Data, Landolt Börnstein, edited by A.

G. Wilson and Yoffe [4], Rao and Pisharody [5], and Balchin [6]. 1. STRUCTURE AND POLYTYPES The layered TMDCs have composition where T is a group IV, V, or VI transition metal and X is S, Se or Te. The basic building blocks of these materials are sandwiches, each consisting of a hexagonal sheet of transition metal atoms between two similar sheets of chalcogen atoms. These sandwiches, with strong internal bonds, are usually referred to as “layers”, although each of them is actually composed of three atomic layers.

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